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Prof. Dr. Martin Goez and Christoph Kerzig Counterintuitive Influence of Protonation on Radical-Anion Photoionization Angewandte Chemie International Edition 51

Version of Record online: 4 NOV 2012 | DOI: 10.1002/anie.201206605

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Protonation of a radical anion M.− greatly facilitates its green-light photoionization despite much less favorable energetics for the resulting ketyl radical MH.. The state symmetry of the radical species absorbing the ionizing photon might provide an explanation.

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