Prof. Dr. Martin Goez and Christoph Kerzig Counterintuitive Influence of Protonation on Radical-Anion Photoionization Angewandte Chemie International Edition 51
Protonation of a radical anion M.− greatly facilitates its green-light photoionization despite much less favorable energetics for the resulting ketyl radical MH.. The state symmetry of the radical species absorbing the ionizing photon might provide an explanation.
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