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Tyler J. Carter, Dr. Jeff W. Kampf and Prof. Nathaniel K. Szymczak Reduction of Borazines Mediated by Low-Valent Chromium Species Angewandte Chemie International Edition 51

Version of Record online: 14 NOV 2012 | DOI: 10.1002/anie.201206668

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Recharging spent BN fuel: {Cr(CO)3} mediates the reduction of borazines by hydride and methyl nucleophiles to generate anionic complexes of dearomatized hexamethylborazine. Subsequent quenching leads to the release of a substituted cyclotriborazane, successfully demonstrating the stepwise reduction of a B[DOUBLE BOND]N bond.

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