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Jun Xu, Bin Xiao, Chuan-Qi Xie, Dong-Fen Luo, Prof. Lei Liu and Prof. Yao Fu Copper-Promoted Trifluoromethylation of Primary and Secondary Alkylboronic Acids Angewandte Chemie International Edition 51

Article first published online: 9 NOV 2012 | DOI: 10.1002/anie.201206681

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New couple: The Cu-promoted trifluoromethylation of primary and secondary alkylboronic acids with TMSCF3 extends the scope of transition-metal-catalyzed trifluoromethylation reactions to sp3-hybridized carbon centers. It also represents one of the first examples for Cu-catalyzed C[BOND]C cross-coupling reactions of alkylboronic acid derivatives.

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