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Dr. Di Zhu, Daniel J. Kozera, Kelly D. Enns and Dr. Peter H. M. Budzelaar Cascade Activation of Si[BOND]H, C[BOND]H, and Si[BOND]C Bonds at a Rhodium β-Diiminate Complex Angewandte Chemie International Edition 51

Article first published online: 4 NOV 2012 | DOI: 10.1002/anie.201206751

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The coupling of HSiEt3 and related silanes to β-diiminate ligands is achieved through a series of Si[BOND]H, C[BOND]H, and Si[BOND]C bond-breaking and bond-forming reactions. Complex 1 (see scheme) loses an Et(Si) group as ethane and couples the remaining SiEt2H fragment to a benzylic methyl group of the ligand skeleton. According to DFT calculations, the reaction involves silylene intermediates.

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