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Crispin Lichtenberg, Fangfang Pan, Dr. Thomas P. Spaniol, Prof. Dr. Ulli Englert and Prof. Dr. Jun Okuda The Bis(allyl)bismuth Cation: A Reagent for Direct Allyl Transfer by Lewis Acid Activation and Controlled Radical Polymerization Angewandte Chemie International Edition 51

Version of Record online: 14 NOV 2012 | DOI: 10.1002/anie.201206782

Thumbnail image of graphical abstract

A positive effect: The bis(allyl)bismuth cation (see picture) in [Bi(C3H5)2(thf)2][B(C6H3Cl2)4] is superior to neutral tris(allyl)bismuth in the additive-free allylation of unsaturated C-heteroatom functionalities and the controlled living radical polymerization of activated olefins.

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