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Dr. Motoki Ito, Itsuki Itani, Yosuke Toyoda, Dr. Koji Morimoto, Dr. Toshifumi Dohi and Prof. Dr. Yasuyuki Kita Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation into Functionalized Aryl Boronates Angewandte Chemie International Edition 51

Article first published online: 8 NOV 2012 | DOI: 10.1002/anie.201206917

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Dormant boron awaits its true destiny in diaryliodonium salts synthesized from aryl boronate derivatives according to two alternative general methods with hypervalent iodine(III) reagents and fluoroalcohol solvents: transformation of an aryl C[BOND]H bond and boron–iodine(III) exchange (see scheme; FG=functional group). The salts could be functionalized by both catalyst-free and metal-catalyzed reactions without loss of the boron functionality.

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