E-mail a Wiley Online Library Link

Dongqi Wang, Fen Wang, Dr. Guoyong Song and Prof. Xingwei Li Diverse Reactivity in a Rhodium(III)-Catalyzed Oxidative Coupling of N-Allyl Arenesulfonamides with Alkynes Angewandte Chemie International Edition 51

Article first published online: 29 OCT 2012 | DOI: 10.1002/anie.201206918

Thumbnail image of graphical abstract

Olefinic C[BOND]H activation of N-allyl sulfonamides in the presence of [{RhCp*Cl2}2] (Cp*=Me5C5) enabled their oxidative coupling with alkynes to generate 1,2-dihydropyridines, pyridines, and cyclopentenones (see scheme; Ts=p-toluenesulfonyl). The type of highly substituted product formed was controlled by the substitution of the allyl group and the reaction conditions.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field