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Hongyan Ye, Zhenpin Lu, Di You, Dr. Zhenxia Chen, Prof. Zhen Hua Li and Prof. Huadong Wang Frustrated Lewis Pair Induced Boroauration of Terminal Alkynes Angewandte Chemie International Edition 51

Version of Record online: 18 OCT 2012 | DOI: 10.1002/anie.201206927

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Golden frustration: The facile activation of terminal alkynes with a frustrated Lewis pair (1 and 1,4-diazabicyclo[2.2.2]octane (DABCO)) enables the development of an efficient boroauration reaction. This process can be achieved directly from alkynes, a hydroborane, [PPh3AuCl], and an organic base. ArF=2,4,6-tris(trifluoromethyl)phenyl.

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