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Lei Xia, Xian-Jin Zeng, Hong-Kai Li, Bin Wu and Prof. Dr. Shan Xi Tian Orientation Effect in the Low-Energy Electron Attachment to the Apolar Carbon Tetrafluoride Molecule Angewandte Chemie International Edition 52

Article first published online: 26 NOV 2012 | DOI: 10.1002/anie.201206948

Thumbnail image of graphical abstract

Electron capture at the carbon–fluorine σ* antibonding orbital accounts for the vector correlations between fragments F and CF3 or F and CF3 in two complementary dissociation pathways after electron attachment to CF4. An orientation effect in the low-energy electron attachment is observed by velocity mapping (see picture; C black, F blue).

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