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Victor Mougel, Clément Camp, Dr. Jacques Pécaut, Christophe Copéret, Prof. Laurent Maron, Dr. Christos E. Kefalidis and Dr. Marinella Mazzanti Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation Angewandte Chemie International Edition 51

Article first published online: 4 NOV 2012 | DOI: 10.1002/anie.201206955

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Siloxides can support U! …in the reduction of small molecules with uranium complexes. The treatment of [U{N(SiMe3)2}3] with HOSi(OtBu)3 (3 equiv) yielded a novel homoleptic uranium(III) siloxide complex 1, which acted as a two-electron reducing agent toward CS2 and CO2 (see scheme). Complex 1 also reduced toluene to afford a diuranium inverted-sandwich complex.

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