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Dr. Shohei Tashiro, Koji Matsuoka, Ai Minoda and Prof. Dr. Mitsuhiko Shionoya Metallo-Foldamers with Backbone-Coordinative Oxime Peptides: Control of Secondary Structures Angewandte Chemie International Edition 51

Article first published online: 14 NOV 2012 | DOI: 10.1002/anie.201206968

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Metal-mediated secondary structures of peptide-based foldamers were constructed using artificial backbone-coordinative oxime peptides. Complexation of the peptides with PdII afforded several mononuclear and dinuclear secondary structures such as helices and hairpins as confirmed by single-crystal XRD and NMR analyses (see picture).

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