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Prof. Dr. Takeaki Iwamoto, Fumiya Hirakawa and Dr. Shintaro Ishida A Two-Coordinate Palladium Complex with Two Dialkylphosphinyl Ligands Angewandte Chemie International Edition 51

Article first published online: 24 OCT 2012 | DOI: 10.1002/anie.201206997

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Navy blue crystals of a two-coordinate homoleptic palladium complex with two phosphinyl radical ligands was synthesized by a simple ligand-exchange reaction. Significant π interactions between orbitals of Pd and the SOMO of phosphinyl radicals are responsible for the diamagnetic character, the intense blue color, and short P[BOND]Pd distances. Hydrogenation of the complex gave the corresponding bis(dialkylhydrophosphine)palladium complex.

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