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Dr. Shuhui Yow, Sarah J. Gates, Dr. Andrew J. P. White and Dr. Mark R. Crimmin Zirconocene Dichloride Catalyzed Hydrodefluorination of C sp 2[BOND]F bonds Angewandte Chemie International Edition 51

Article first published online: 6 NOV 2012 | DOI: 10.1002/anie.201207036

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A two-metal job: Four-coordinate aluminum dihydrides such as 1 are reported as terminal reductants for the selective title reaction. The heterobimetallic complex 2 has been isolated and shown to be catalytically competent.

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