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Dr. Łukasz Albrecht, Dr. Gustav Dickmeiss, Dr. Christian F. Weise, Dr. Carles Rodríguez-Escrich and Prof. Dr. Karl Anker Jørgensen Dienamine-Mediated Inverse-Electron-Demand Hetero-Diels–Alder Reaction by Using an Enantioselective H-Bond-Directing Strategy Angewandte Chemie International Edition 51

Version of Record online: 12 NOV 2012 | DOI: 10.1002/anie.201207122

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Giving directions: Optically active dihydropyrans bearing three contiguous stereogenic centers can be efficiently prepared by the title reaction. High stereo- and regiocontrol can be achieved by employing a bifunctional H-bond-directing aminocatalyst.

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