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Xin Bao, Dr. Helena J. Shepherd, Dr. Lionel Salmon, Dr. Gábor Molnár, Prof. Dr. Ming-Liang Tong and Dr. Azzedine Bousseksou The Effect of an Active Guest on the Spin Crossover Phenomenon Angewandte Chemie International Edition 52

Article first published online: 7 NOV 2012 | DOI: 10.1002/anie.201207218

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Throw the switch: A new strategy for regulating spin crossover (SCO) properties by the control of an active guest molecule is proposed. As a proof of concept, maleic anhydride was incorporated into a microporous {Fe(pyrazine)[Pt(CN)4]} framework material and chemically switched to maleic acid, thus modifying the SCO properties (see picture).

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