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Dr. Christopher J. Shaffer, Dr. Ágnes Révész, Dr. Detlef Schröder, Ing. Lukáš Severa, Dr. Filip Teplý, Dr. Emilie-Laure Zins, Mgr. Lucie Jašíková and Dr. Jana Roithová Inside Back Cover: Can Hindered Intramolecular Vibrational Energy Redistribution Lead to Non-Ergodic Behavior of Medium-Sized Ion Pairs? (Angew. Chem. Int. Ed. 40/2012) Angewandte Chemie International Edition 51

Version of Record online: 26 SEP 2012 | DOI: 10.1002/anie.201207222

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Too much heat in non-covalent complexes leads to non-ergodic behavior in ion pairs of nitrogen-containing cations with triflate counterions. In their Communication on page 10050 ff., D. Schröder et al. show by means of infrared spectroscopy of mass-selected ions that the effect is caused by incomplete intramolecular vibrational energy distribution, leading to a local “overheating” of the triflate counterions. PS: Find the hidden dedication in the picture! The puzzle will be solved on the homepage of ChemViews Magazine (http://www.chemviews.org).

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