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Qing Zhou, Dr. Meirong Hu, Dr. Wei Zhang, Dr. Li Jiang, Prof. Dr. Sarah Perrett, Juanzuo Zhou and Prof. Dr. Jiangyun Wang Probing the Function of the Tyr-Cys Cross-Link in Metalloenzymes by the Genetic Incorporation of 3-Methylthiotyrosine Angewandte Chemie International Edition 52

Version of Record online: 29 NOV 2012 | DOI: 10.1002/anie.201207229

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Efficient multiple-electron redox reactions are performed by galactoase oxidase, cysteine dioxygenase, sulfite reductase, and cytochrome c nitrite reductase. A post-translationally modified tyrosine–cysteine cross-link (Tyr-Cys) in their active sites is essential for their functions.

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