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Dr. Chia-Hsiang Chen, Dr. Wen-Yann Yeh, Yi-Hung Liu and Dr. Gene-Hsiang Lee [(μ-H)3Re3(CO)9(η2,η2,η2-Sc2C2@C3v(8)-C82)]: Face-Capping Cluster Complex of an Endohedral Fullerene Angewandte Chemie International Edition 51

Version of Record online: 14 NOV 2012 | DOI: 10.1002/anie.201207261

Thumbnail image of graphical abstract

Like a miniature trophy, the complex pictured was obtained as the sole product from the reaction of Sc2C2@C3v(8)-C82 and [(μ-H)3Re3(CO)11(NCMe)] and characterized by IR, visible/near-infrared, and NMR spectroscopy, mass spectrometry, and X-ray diffraction. Coordination of the Re3 cluster to the unique hexagon oriented perpendicular to the C3 axis of the fullerene core altered the geometry and electronic properties of Sc2C2@C3v(8)-C82.

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