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Prof. Dr. J. Stephen Clark, Dr. Alistair Boyer, Anthony Aimon, Paloma Engel García, Dr. David M. Lindsay, Andrew D. F. Symington and Yves Danoy Organocatalytic Synthesis of Highly Substituted Furfuryl Alcohols and Amines Angewandte Chemie International Edition 51

Article first published online: 24 OCT 2012 | DOI: 10.1002/anie.201207300

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Top cat! Tetrahydrothiophene is an efficient organocatalyst for the synthesis of highly substituted furfuryl products from readily accessible electron-poor enynes under neutral reaction conditions. This process is applicable to a wide range of nucleophiles and enynes and can be used in a domino organocatalysis sequence.

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