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Alexander Hübner, Dr. Martin Diefenbach, Dr. Michael Bolte, Dr. Hans-Wolfram Lerner, Prof. Dr. Max C. Holthausen and Prof. Dr. Matthias Wagner Confirmation of an Early Postulate: B[BOND]C[BOND]B Two-Electron–Three-Center Bonding in Organo(hydro)boranes Angewandte Chemie International Edition 51

Version of Record online: 14 NOV 2012 | DOI: 10.1002/anie.201207335

Thumbnail image of graphical abstract

Finally, boron did it too: The first example of a dimeric organyl(hydro)borane with a B-B-bridging aryl ring has been elucidated (see picture; B green/blue, C black/gray). It features a B[BOND]C[BOND]B two-electron–three-center bond and a largely unperturbed aromatic π-electron system.

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