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Dr. Kazunobu Igawa, Daisuke Yoshihiro, Nobumasa Ichikawa, Naoto Kokan and Prof. Dr. Katsuhiko Tomooka Catalytic Enantioselective Synthesis of Alkenylhydrosilanes Angewandte Chemie International Edition 51

Article first published online: 7 NOV 2012 | DOI: 10.1002/anie.201207361

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Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety.

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