Dr. Robert Evans, Zhaoxia Deng, Alexandria K. Rogerson, Dr. Andy S. McLachlan, Jeff J. Richards, Dr. Mathias Nilsson and Prof. Gareth A. Morris Quantitative Interpretation of Diffusion-Ordered NMR Spectra: Can We Rationalize Small Molecule Diffusion Coefficients? Angewandte Chemie International Edition 52
Appealingly simple: A new method is described that allows the diffusion coefficient of a small molecule to be estimated given only the molecular weight and the viscosity of the solvent used. This method makes possible the quantitative interpretation of the diffusion domain of diffusion-ordered NMR spectra (see picture).
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