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Keisuke Doi, Eijiro Togano, Dr. Sotiris S. Xantheas, Ryuzo Nakanishi, Prof. Takashi Nagata, Prof. Takayuki Ebata and Dr. Yoshiya Inokuchi Microhydration Effects on the Intermediates of the SN2 Reaction of Iodide Anion with Methyl Iodide Angewandte Chemie International Edition 52

Article first published online: 30 JAN 2013 | DOI: 10.1002/anie.201207697

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Water gets in the way: Hydrated I(CH3I) complexes, I(CH3I)(H2O)1–3, are investigated by IR photodissociation spectroscopy to examine the stable structures of the intermediates of the I+CH3I[RIGHTWARDS ARROW]ICH3+I SN2 reaction under hydrated conditions. The structures and the energetics of the complexes suggest that just one or two H2O molecules will effectively inhibit this SN2 reaction.

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