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Dr. Rowan D. Young, Prof. Dr. Anthony F. Hill, Dr. Germán E. Cavigliasso and Prof. Dr. Robert Stranger [(μ-C){Re(CO)2(η-C5H5)}2]: A Surprisingly Simple Bimetallic Carbido Complex Angewandte Chemie International Edition 52

Article first published online: 19 FEB 2013 | DOI: 10.1002/anie.201207731

Thumbnail image of graphical abstract

It's easy to C: The reaction of [Re(CO)2(CS)(η-C5H5)] with [Re(CO)2(thf)(η-C5H5)] affords the disulfur complex [Re(CO)22-S2)(η-C5H5)] and the remarkably simple μ-carbido complex [(μ-C){Re(CO)2(η-C5H5)}2], which has been structurally characterized and computationally investigated (see picture; black C, white H, red O, green Re).

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