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Prof. Christina Moberg Mechanism of Diphenylprolinol Silyl Ether Catalyzed Michael Addition Revisited—but Still Controversial Angewandte Chemie International Edition 52

Article first published online: 3 JAN 2013 | DOI: 10.1002/anie.201207775

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Two views: The mechanism of the conjugate addition of linear aldehydes to nitro olefins has been investigated by two research groups. In spite of extensive experimental data, important questions remain unanswered (see scheme; TMS=trimethylsilyl, En=enamine).

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