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Dr. Kenji Uchida, Takahiro Ogawa, Yoshinori Yasuda, Hiraku Mimura, Dr. Teppei Fujimoto, Prof. Dr. Tohru Fukuyama, Dr. Toshiyuki Wakimoto, Dr. Tomohiro Asakawa, Dr. Yoshitaka Hamashima and Prof. Dr. Toshiyuki Kan Stereocontrolled Total Synthesis of (+)-UCS1025A Angewandte Chemie International Edition 51

Version of Record online: 9 NOV 2012 | DOI: 10.1002/anie.201207800

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Under control: A stereocontrolled total synthesis of (+)-UCS1025A, a potent telomerase inhibitor, was achieved. The synthesis features an intramolecular Diels–Alder reaction, a tandem Staudinger/aza-Wittig reaction, and stereoselective construction of the hemiaminal moiety facilitated by neighboring-group participation.

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