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Dr. Rusheng Yuan, Shaolong Fan, Huaxi Zhou, Dr. Zhengxin Ding, Dr. Sen Lin, Prof. Dr. Zhaohui Li, Dr. Zizhong Zhang, Dr. Chao Xu, Prof. Ling Wu, Prof. Xuxu Wang and Prof. Xianzhi Fu Chlorine-Radical-Mediated Photocatalytic Activation of C[BOND]H Bonds with Visible Light Angewandte Chemie International Edition 52

Version of Record online: 26 NOV 2012 | DOI: 10.1002/anie.201207904

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Going green on the cheap: A highly effective photocatalytic reaction mode involving chlorine radicals generated on chlorinated BiOBr/TiO2 upon irradiation with visible light enabled selective transformations of alkanes into functionalized products through the formation of C[BOND]O and C[BOND]C bonds (see scheme). This process provides a sustainable strategy for direct C[BOND]H functionalization under mild conditions.

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