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Dr. Bo Liu, M. Sc. Min Tu and Prof. Dr. Roland A. Fischer Metal–Organic Framework Thin Films: Crystallite Orientation Dependent Adsorption Angewandte Chemie International Edition 52

Version of Record online: 12 FEB 2013 | DOI: 10.1002/anie.201207908

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Well oriented: Preferred [100] and [001] orientations of metal–organic framework crystallites, [Cu2(ndc)2(dabco)] (ndc=1,4-naphthalenedicarboxylate, dabco=1,4-diazabicyclo[2.2.2]octane), attached to surfaces were fabricated. Different pore openings owing to anisotropic properties of [Cu2(ndc)2(dabco)] result in oriented thin films exhibiting distinct adsorption kinetics for volatile organic compounds.

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