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Dr. Evelyn Hartmann and Prof. Dr. Ruth M. Gschwind The Supramolecular Balance for Transition-Metal Complexes: Assessment of Noncovalent Interactions in Phosphoramidite Palladium Complexes Angewandte Chemie International Edition 52

Article first published online: 11 JAN 2013 | DOI: 10.1002/anie.201208021

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The virtue of enantiomers: A general method has been developed for measuring the individual contributions of noncovalent interactions within transition-metal complexes and dissecting them from electronic effects. On Pd complexes with one enantiopure and two enantiomeric phosphoramidite ligands, it was experimentally shown that modulations in extended CH–π and π–π interaction interfaces provide a ΔΔG value that is significant for stereoselection.

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