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Dr. Robert Podgajny, Szymon Chorazy, Dr. Wojciech Nitek, Dr. Michał Rams, Anna M. Majcher, Bartosz Marszałek, Dr. Jan Żukrowski, Prof. Dr. Czesław Kapusta and Prof. Dr. Barbara Sieklucka Co–NC–W and Fe–NC–W Electron-Transfer Channels for Thermal Bistability in Trimetallic {Fe6Co3[W(CN)8]6} Cyanido-Bridged Cluster Angewandte Chemie International Edition 52

Version of Record online: 26 NOV 2012 | DOI: 10.1002/anie.201208023

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Which way to choose? The trimetallic cyanide-bridged Fe6Co3W6 cluster serves as a molecular platform for two cooperating electron-transfer channels, WV–CN–HSCoII⇄WIV–CN–LSCoIII and WV–CN–HSFeII⇄WIV–CN–HSFeIII. {CoII3FeII6[WV(CN)8]6(MeOH)24}⋅x MeOH has a first-order unique spin transition with thermal charge-transfer-induced spin transition and spin bistability that is due to a specific distribution of Co and Fe sites.

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