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Bingrui Song, Dr. Thomas Knauber and Prof. Dr. Lukas J. Gooßen Decarboxylative Cross-Coupling of Mesylates Catalyzed by Copper/Palladium Systems with Customized Imidazolyl Phosphine Ligands Angewandte Chemie International Edition 52

Article first published online: 5 FEB 2013 | DOI: 10.1002/anie.201208025

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The activation of the inert C[BOND]O bonds in mesylates through the use of a new class of imidazolyl phosphines allows the decarboxylative coupling of aryl mesylates as well as polysubstituted alkenyl mesylates. Variation of the ligands leads to two complementary methods providing the corresponding biaryls and polysubstituted olefins in good yields.

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