E-mail

E-mail a Wiley Online Library Link

Prof. Dr. Giulia Licini and Dr. Cristiano Zonta Revisiting the Hammett ρ Parameter for the Determination of Philicity: Nucleophilic Substitution with Inverse Charge Interaction Angewandte Chemie International Edition 52

Version of Record online: 1 FEB 2013 | DOI: 10.1002/anie.201208045

Thumbnail image of graphical abstract

Too OT to handle? In oxygen transfer (OT) reactions the inversion of the ρ value is not representative of a change in mechanism. Substituents bonded to aromatic sulfoxides have the opposite effect on the rates of oxidation depending on whether the reaction is dominated by electrostatic or orbital-overlap effects (see picture).

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH