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Iacovos N. Michaelides and Prof. Dr. Darren J. Dixon Catalytic Stereoselective Semihydrogenation of Alkynes to E-Alkenes Angewandte Chemie International Edition 52

Article first published online: 17 DEC 2012 | DOI: 10.1002/anie.201208120

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Less is more: Significant advancements have been made in recent years in the development of the E-selective, catalytic, functional-group-tolerant semihydrogenation of alkynes to E-alkenes through transition-metal catalysis (see scheme). For this type of catalysis, the use of mononuclear metal catalysts is superior to that of multinuclear metal catalysts.

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