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Tomohiro Higashino, Byung Sun Lee, Jong Min Lim, Prof. Dr. Dongho Kim and Prof. Dr. Atsuhiro Osuka A Möbius Antiaromatic Complex as a Kinetically Controlled Product in Phosphorus Insertion to a [32]Heptaphyrin Angewandte Chemie International Edition 51

Version of Record online: 19 NOV 2012 | DOI: 10.1002/anie.201208147

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Singly twisted Möbius antiaromatic [34]heptaphyrin A and doubly twisted Hückel aromatic [34]heptaphyrin B were formed by a phosphorus insertion reaction. A rearranges thermally to give the more stable B with P[DOUBLE BOND]O migration from NNN to NNC, and thus A is a rare case of a kinetically controlled Möbius antiaromatic molecule.

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