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Dipl.-Chem. Markus W. Schneider, Prof. Dr. Iris M. Oppel, Dr. Alexandra Griffin and Dr. Michael Mastalerz Post-Modification of the Interior of Porous Shape-Persistent Organic Cage Compounds Angewandte Chemie International Edition 52

Article first published online: 19 FEB 2013 | DOI: 10.1002/anie.201208156

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Interior decorating: A post-synthetic method allows porous organic cage compounds to be prepared with functionalized interior cavities. The approach produces modified cage compounds in quantitative yield and opens the possibility of preparing organic alloys with different functionality. The solution-based technique shows the advantage of solubility, an inherent property of porous materials derived from discrete organic molecules.

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