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Paul W. Dunk, Dr. Antonio Rodríguez-Fortea, Dr. Nathan K. Kaiser, Prof. Hisanori Shinohara, Prof. Josep M. Poblet and Prof. Harold W. Kroto Formation of Heterofullerenes by Direct Exposure of C60 to Boron Vapor Angewandte Chemie International Edition 52

Version of Record online: 6 DEC 2012 | DOI: 10.1002/anie.201208244

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Introducing boron: Heterofullerenes that incorporate boron have been scarcely studied because a formation route from C60 is not known. It is now reported that C59B, an electronically closed-shell species, is formed directly from pristine C60 in the gas-phase by facile atom exchange reactions.

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