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Le Zhao, Dr. Chihiro Tsukano, Dr. Eunsang Kwon, Prof. Dr. Yoshiji Takemoto and Prof. Dr. Masahiro Hirama Total Syntheses of Complanadines A and B Angewandte Chemie International Edition 52

Version of Record online: 20 DEC 2012 | DOI: 10.1002/anie.201208297

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Twice as nice: Total syntheses of dimeric alkaloids, (−)-complanadines A (1) and B (2), were achieved from (−)-lycodine. The unsymmetrical motif was assembled through direct arylation of the pyridine N-oxide. The absolute configuration and specific rotations of complanadines A and B were identified. Cbz=Benzyloxycarbonyl.

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