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Dr. Nicky Savjani, Dragoş-Adrian Roşca, Dr. Mark Schormann and Prof. Dr. Manfred Bochmann Gold(III) Olefin Complexes Angewandte Chemie International Edition 52

Article first published online: 23 NOV 2012 | DOI: 10.1002/anie.201208356

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Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for AuIII–Ag interactions.

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