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Dr. Shuichi Suzuki, Kohei Yoshida, Dr. Masatoshi Kozaki and Prof. Dr. Keiji Okada Syntheses and Structural Studies of Tris(N-phenothiazinyl)borane and Its Radical Cation Angewandte Chemie International Edition 52

Article first published online: 21 JAN 2013 | DOI: 10.1002/anie.201208392

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A radical comparison: The neutral (1) and radical cation (1.+) forms of tris(N-phenothiazinyl)borane were prepared and their molecular structures and spectral properties investigated. The results established that 1.+ possessed a localized radical cation on one of the phenothiazine (PTZ) rings. The crystal structure of 1.+ showed elongation of the B[BOND]N bond bound to the PTZ.+ ring (B[BOND]N1: 1.53 Å).

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