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Dr.  Ming Hu, Dr. Shinsuke Ishihara and Prof. Dr. Yusuke Yamauchi Bottom-Up Synthesis of Monodispersed Single-Crystalline Cyano-Bridged Coordination Polymer Nanoflakes Angewandte Chemie International Edition 52

Version of Record online: 3 DEC 2012 | DOI: 10.1002/anie.201208501

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A two-dimensional morphology characterizes the nanoflakes that are obtained in the bottom-up synthesis of a single-crystalline coordination polymer, Ni(H2O)2[Ni(CN)4]⋅x H2O. The 10 nm-thick nanoflakes are well-dispersed in solution and have a very high accessible surface area (240 m2 g−1). Thermal treatment leads to nanoporous NiO with retention of the original flake morphology.

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