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Ayham Tohmé, Dr. Guillaume Grelaud, Dr. Gilles Argouarch, Dr. Thierry Roisnel, Dr. Stéphanie Labouille, Dr. Duncan Carmichael and Dr. Frédéric Paul Redox-Induced Reversible P[BOND]P Bond Formation to Generate an Organometallic σ4λ4-1,2-Biphosphane Dication Angewandte Chemie International Edition 52

Version of Record online: 14 MAR 2013 | DOI: 10.1002/anie.201208682

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Twice the fun: Dimeric FeII diphosphonium bis(alkynyl) complexes are formed by oxidation of the corresponding FeII alkynyl phosphine complexes. The structure of these organometallic diphosphonium salts and their monomeric precursors were established by X-ray crystallography. The P[BOND]P bond can be cleaved by two-electron reduction to regenerate the monomers.

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