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Dr. Matteo Ceppatelli, Prof. Roberto Bini, Dr. Maria Caporali and Dr. Maurizio Peruzzini High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation Angewandte Chemie International Edition 52

Version of Record online: 11 JAN 2013 | DOI: 10.1002/anie.201208684

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A high-pressure job: Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H2, PH3, H3PO2, H3PO4, and H3PO4 (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H2 generation.

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