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Xuan Huang, Liqiang Song, Jiao Xu, Guili Zhu and Prof. Dr. Bo Liu Asymmetric Total Synthesis of Leucosceptroid B Angewandte Chemie International Edition 52

Version of Record online: 11 DEC 2012 | DOI: 10.1002/anie.201208687

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Less stable, but natural: The asymmetric total synthesis of leucosceptroid B (see scheme) has been accomplished in 19 steps. Thermodynamically, this natural product proved to be less stable than its C11 epimer, a synthetic intermediate. This synthesis features a high degree of flexibility, facilitating its application to the preparation of a broad range of other natural derivatives.

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