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Prof. Dr. John Texter, Dr. Kejian Bian, Dan Chojnowski and Joe Byrom Organosiloxane Supramolecular Liquids—Surface-Energy-Driven Phase Transitions Angewandte Chemie International Edition 52

Article first published online: 22 JAN 2013 | DOI: 10.1002/anie.201208725

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Autocondensation of organoalkoxysilanes and subsequent anion exchange produces organosiloxane supramolecular liquids which are core-free and solvent-free nanoparticle nanofluids. This hybrid supramolecular liquid, [C81H156NO3S(SiO[2>x>3/2])]y, exhibits (see TEM image; 200 nm width) interparticle menisci and softness (from imputed deformations) of interparticle potential.

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