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Dr. Muhammad Sajid, Lisa-Maria Elmer, Christoph Rosorius, Dr. Constantin G. Daniliuc, Prof. Dr. Stefan Grimme, Dr. Gerald Kehr and Prof. Dr. Gerhard Erker Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates Angewandte Chemie International Edition 52

Article first published online: 15 JAN 2013 | DOI: 10.1002/anie.201208750

Thumbnail image of graphical abstract

A new reaction pathway: Carbon monoxide is readily reduced by Piers' borane at a frustrated Lewis pair (FLP) to yield a formylborane stabilized by the FLP (see picture). This reaction may be considered a typical example of efficient activation of a small molecule by a FLP.

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