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Dr. Arkaitz Correa, Dr. Josep Cornella and Dr. Ruben Martin Nickel-Catalyzed Decarbonylative C[BOND]H Coupling Reactions: A Strategy for Preparing Bis(heteroaryl) Backbones Angewandte Chemie International Edition 52

Article first published online: 3 JAN 2013 | DOI: 10.1002/anie.201208843

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Activation à la carte: The direct arylation of heteroarenes was accomplished by employing aromatic esters as effective coupling partners under nickel catalysis (see scheme; Z=O, S). The key process implies an unconventional and unprecedent Ni-catalyzed decarbonylative coupling utilizing cost-efficient nickel catalysts.

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