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Dipak Kumar Roy, Dr. Shubhankar Kumar Bose, R. S. Anju, Bijan Mondal, V. Ramkumar and Prof. Sundargopal Ghosh Boron Beyond the Icosahedral Barrier: A 16-Vertex Metallaborane Angewandte Chemie International Edition 52

Version of Record online: 4 FEB 2013 | DOI: 10.1002/anie.201208849

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A neutral metallaborane comprising a Rh4B12 polyhedron with icosioctahedron geometry with 16 vertices and 28 triangular faces was prepared (see structure; Rh: red, B: green). The cage has the shape of a 12-membered truncated tetrahedron with four capped hexagonal faces.

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