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Katie G. Maskill, Dr. Jonathan P. Knowles, Dr. Luke D. Elliott, Prof. Dr. Roger W. Alder and Prof. Dr. Kevin I. Booker-Milburn Complexity from Simplicity: Tricyclic Aziridines from the Rearrangement of Pyrroles by Batch and Flow Photochemistry Angewandte Chemie International Edition 52

Version of Record online: 10 JAN 2013 | DOI: 10.1002/anie.201208892

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Molecular acrobatics: Irradiation of N-butenyl-substituted pyrroles that bear an electron-withdrawing group leads to complex tricyclic aziridines through an unprecedented photocycloaddition–rearrangement sequence. Gram quantities of these complex products could be produced by using a bespoke flow reactor (see picture, FEP=fluorinated ethylene propylene).

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