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Prof. Dr. Reinhard W. Hoffmann and Prof. Dr. Keisuke Suzuki A “Hot, Energized” Benzyne Angewandte Chemie International Edition 52

Version of Record online: 11 JAN 2013 | DOI: 10.1002/anie.201209041

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Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular [4+2] cycloaddition between a diyne and an (electronically activated) alkyne also provides a new route to generate arynes (see scheme).

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