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Yi Jiang, Dr. Fei Li, Biaobiao Zhang, Dr. Xiaona Li, Xiaohong Wang, Fang Huang and Prof. Licheng Sun Promoting the Activity of Catalysts for the Oxidation of Water with Bridged Dinuclear Ruthenium Complexes Angewandte Chemie International Edition 52

Version of Record online: 13 FEB 2013 | DOI: 10.1002/anie.201209045

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Solar fuels: Dinuclear ruthenium catalysts prepared from two covalently bridged monomeric catalytic units show outstanding activities towards the oxidation of water with high turnover numbers up to 43 000 and turnover frequencies up to 40 s−1 (see picture). Direct comparison of the performance parameters indicates that the dimers are significantly more active as catalysts than the monomers.

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